https://codepen.io/HughGrovesArup/pen/OJLadYp
As can be seen when in a table row the / is misaligned.

The issue doesn't appear on https://katex.org/. My hunch is that codepen.io's CSS is affect ours somehow. I wasn't able to figure out what style was responsible though. :( Once we figure that out we should be able to guard against it. We should probably add a bunch of reset params to .katex in katex.less to reset all external styles.
The places where I have actually encountered the issue are in a VS code extension that utilises a webview (like an iframe) and inside a vue.js component.
The issue does not appear on katex.org - but is that just because it's not within
@HughGrovesArup: Removing the td and tr means the math block is removed from the table, so that's why it works.
I did some testing.
(1) Removing ALL of codepen's styles gave the following (with the second set of equations being in p tags, not in a table):

So that's not it.
(2) I then tried the code in various versions:
0.9.0 (not quite right since the neq is too far right, but at least looks OK)

0.10.0

0.10.2

So seems it's a KaTeX issue.
This is due to vlist using a table layout and border-collapse which affects it is set to separate in table tags. I've opened a PR. Thank you for reporting!