Inside the developer tools inspect element, when selecting the option to preview the site using device toolbar. Setting the preset size to Laptop - 1024px or any of the higher options (All presets below work normally) Hovering over any node in the elements UI will show the highlight/tooltip in the incorrect location not aligned with the selected node. Also occurring if the option to hover over the preview is enabled.
tl;dr - Enabling device toolbar, when setting tab to "Laptop" and above, hovering over any node -- highlight/tooltip is not aligned correctly.
inspect element or ctrl + shift + i, once opened select the option to Toggle device toolbar. Once the preview pops up change the size to Laptop - 1024pxBrave

Chrome

Easily reproduced
Brave | 0.63.55 Chromium: 74.0.3729.131聽(Official Build)聽(64-bit)
-- | --
Revision | 518a41c1fa7ce1c8bb5e22346e82e42b4d76a96f-refs/branch-heads/3729@{#954}
OS | Windows聽10 OS Build 17763.475
Occurs on all channels (Release/Beta/Dev/Nightly)
Another issue with developer tools - #3199
cc: @LaurenWags is this related to responsive mode reported in a community thread?
@rebron I believe so. Here's the thread:
https://community.brave.com/t/inspect-element-dev-tools-broken-in-responsive-mode/59811
Some extra info -
This doesn't seem to be related to 1024px but rather, the inspector zoom. Anytime the zoom changes to anything but 100%, the inspector breaks.

Looks like is working correctly on version 0.65.118 on OSX.
Working correctly on both macOS and Windows running latest release builds (0.65.118)
@LaurenWags / @rebron
Awesome! Thanks for confirming, @manrueda @BhuZha! 馃帀
Most helpful comment
Some extra info -
This doesn't seem to be related to
1024pxbut rather, the inspector zoom. Anytime the zoom changes to anything but100%, the inspector breaks.